One place where ultegra may be "better" than DA is in the crank.
Besides price, with DA triple crank, the small, inner granny chairing
is limited to one size due to the proprietary 92mm bolt pattern. Thus,
you can only get a 30t chainring from Shimano.
In contast, with the ultegra triple crank, it has a standard 74mm bolt
pattern for its granny chainring. That means you can get an inner
granny chainring from 24-30t. Further, you are not limited to one
manufacturer. You can get a 74mm chainring from TA, Willow, Salsa,
Engagement, Sugino, Shimano, and, even, glup, Campy!
Another place where ultegra may be "better" than DA is the bb,
especially for 9 speed stuff. Ultegra bb is a sealed cartridge bearing
unit. DA is cup and cone. That means that even on occasions, DA has to
be rebuilt.
One place where DA is better than ultegra is the sti levers. With DA,
you get a 3 year warranty. Ultegra and all other shimano groups only
get 2 years. So, if your DA sti levers go south, within the 3 year
warranty period, you can get it replaced!