Errm one physicist here, and sad though it is I couldn't resist replying 🙂
In theory I don't think you'd save any energy at all, that is if you disregard friction and assume that you're not accelerating or going uphill (I am a physicist remember, we don't do real world!). You have to remember the no matter how heavy the pedal or shoe there's an equal weight on the other end of the crank, so it won't become any easier or harder to spin. Basically on the flat the only influence the weight of the bike has is on the friction between the moving components and between the tyres and the ground.
So if we assume that bike and rider weigh about 80kg, we can use the friction equation F=mu R, where R is the force resultant from the gravitational downforce on bike and rider, F is the frictional force, and mu is the combined friction coefficient, which we assume to be constant.
If we decrease the mass of the bike and rider by 2 grams, then we can say that F2/F1 = (79.998)/(80) = 0.999975 where F1 is the frictional force before massacering your shoes and F2 is the frictional force afterwards.
Since energy is E=Fd where F is the force being overcome (friction in our case) and d is the distance travelled, we find that Power is given by P=Fv where v is the velocity.
Since F2/F1 = 0.999975 we find that
P1/P2 = 0.999975 provided the same speed is assumed.
Put as a percentage you would save 0.0025% when it comes down to your power output.
Go on give me another one 😉